Friday, June 01, 2007

CH3OCF2CHFCL與CHF2OCF2CHFCl對於臭氧的消耗以及全球暖化的潛在影響

林冠宇

摘要
在1970年代初期科學家發現人類大量的使用氟氯碳化物(CFCs)作為冷凍劑、溶劑及汽油添加劑。CFCs在對流層之生命週期從數十年到數萬年不等,並且會垂直擴散進入同溫層。同溫層內足夠的UV光能會使得氟氯碳化物光解產生Cl原子,進而破壞臭氧層(Seinfeld and Pandis, 1998)。有鑑於此,氧化碳氫化合物,特別是鹵化脂類已被廣泛的應用於冷凍劑、清潔劑及醫學用途上。研究人員在實驗室測試氯原子與鹵化脂類的反應速率常數,並探討CH3OCF2CHFCL與CHF2OCF2CHFCl兩種物質對於自然界是否為有害物質,確認其是否適合作為CFCs之替代物質。

Reference:
1. Dalmasso, P. R., Taccone, R. A., Nieto, J. D., Teruel, M. A., Lane, S. I., 2006, CH3OCF2CHFCL and CHF2OCF2CHFCl: Reaction with Cl atoms, atmospheric lifetimes, ozone depletion and global warming potentials, Atmospheric Environment, 40, 7298-7307.
2. Oyaro, N., Sellevåg, S. R., Nielsen, C. J., 2005, Atmospheric chemistry of hydrofluoroethers: Reaction of a series of hydrofluoroethers with OH radicals and Cl atoms, atmospheric lifetimes, and global warming potentials, J. Phys. Chem., 190,337-346.
3.Beach, S.D., Hickson, K.M., Smith, I.W.M., Tuckett, R.P., 2001. Rate constants and Arrhenius parameters for the reactions of OH radicals and Cl atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using the discharge-flow/resonance fluorescence method. Physical Chemistry Chemical Physics 3, 3064–3069.

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